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Published on: September 12, 2014
Panchromatic push-pull chromophores based on triphenylamine as donors for molecular solar cells
Sandra Gómez Esteban1, Pilar de la Cruz, Ana Aljarilla
1Instituto de Nanociencia, Nanotecnología y Materiales Moleculares (INAMOL), Universidad de Castilla-La Mancha, 45071-Toledo, Spain.
Abstract:
Two new push-pull chromophores based on triphenylamine as donor and 2-carboxymethyl-2-cyanomethylenethiazole as acceptor have been synthesized. Both exhibit strong light absorption covering from 300 to 800 nm. Electrochemical studies show HOMO-LUMO gaps of 2.01 and 1.54 eV, making, together with the panchromatic absorption, these systems promising materials in the field of molecular photovoltaic devices.
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