Search research articles

ABOUT JoVE

Overview Leadership Blog JoVE Help Center

AUTHORS

Publishing Process Editorial Board Scope & Policies Peer Review FAQ Submit

LIBRARIANS

Testimonials Subscriptions Access Resources Library Advisory Board FAQ

RESEARCH

JoVE Journal Methods Collections JoVE Encyclopedia of Experiments Archive

EDUCATION

JoVE Core JoVE Business JoVE Science Education JoVE Lab Manual Faculty Resource Center Faculty Site

Terms & Conditions of Use

Related Concept Videos

Capillary Electrophoresis: Applications

Capillary Electrophoresis: Applications

Capillary electrophoretic separations offer various modes, each with unique applications. These modes include capillary zone electrophoresis, capillary gel electrophoresis, capillary array electrophoresis, capillary isoelectric focusing, capillary isotachophoresis, micellar electrokinetic chromatography, and capillary electrochromatography.
Capillary zone electrophoresis (CZE) separates ionic components based on their electrophoretic mobility. It has been used to separate proteins, amino acids,...

Size-Exclusion Chromatography

Size-Exclusion Chromatography

In size-exclusion chromatography (SEC), also known as molecular-exclusion or gel-permeation chromatography, molecules are separated based on their sizes. This technique is important for separating large molecules such as polymers and biomolecules. The two classes of micron-sized stationary phases encountered in SEC are silica particles and cross-linked polymer resin beads. Both materials are porous, but their pore sizes vary significantly.
Silica particles offer advantages such as rigidity,...

Supercritical Fluid Chromatography

Supercritical Fluid Chromatography

Supercritical fluid chromatography (SFC) provides a beneficial substitute for gas chromatography (GC) and liquid chromatography (LC) for certain samples because it merges the top attributes of both techniques. SFC allows the separation and analysis of compounds that GC or LC does not easily manage. These compounds are traditionally nonvolatile or thermally unstable, making GC unsuitable and lacking functional groups required for HPLC analysis.
SFC utilizes a supercritical fluid mobile phase,...

You might also read

Related Articles

Articles linked to this work by shared authors, journal, and citation graph.

Sort by

Same author

Bird-Scented Nests as a Mechanism for Olfactory Homing in a Burrow-Nesting Seabird.

The American naturalist·2026

Same author

In Vino Analytica Scientia 2024: Symposium History, Comment on the 13th Installment and Welcome to the Special Issue.

Journal of agricultural and food chemistry·2025

Same author

A Metabolomics Assay to Diagnose Citrus Huanglongbing Disease and to Aid in Assessment of Treatments to Prevent or Cure Infection.

Phytopathology·2023

Same author

Light scattering from mixtures of interacting, nonionic micelles with hydrophobic solutes.

Soft matter·2022

Same author

A Field Collection of Indigenous Grapevines as a Valuable Repository for Applied Research.

Plants (Basel, Switzerland)·2022

Same author

Feather chemicals contain information about the major histocompatibility complex in a highly scented seabird.

Proceedings. Biological sciences·2022

Search research articles

Related Experiment Video

Updated: May 28, 2026

Tea Aroma Analysis Based on Solvent-Assisted Flavor Evaporation Enrichment

Tea Aroma Analysis Based on Solvent-Assisted Flavor Evaporation Enrichment

Published on: May 26, 2023

Measuring local equilibrium flavor distributions in SDS solution using headspace solid-phase microextraction.

Nathan W Lloyd¹, Eleni Kardaras, Susan E Ebeler

¹Department of Chemical Engineering and Materials Science, University of California, Davis, Davis, California 95616, United States.

The Journal of Physical Chemistry. B

|October 19, 2011

Summary

Solid-phase microextraction (SPME) effectively quantifies limonene partitioning in sodium dodecyl sulfate (SDS) micellar solutions. The partition coefficient varies with limonene concentration, indicating micelle swelling and microemulsion formation.

More Related Videos

Profiling Volatile Compounds in Blackcurrant Fruit using Headspace Solid-Phase Microextraction Coupled to Gas Chromatography-Mass Spectrometry

Profiling Volatile Compounds in Blackcurrant Fruit using Headspace Solid-Phase Microextraction Coupled to Gas Chromatography-Mass Spectrometry

Published on: June 9, 2021

Capturing Actively Produced Microbial Volatile Organic Compounds from Human-Associated Samples with Vacuum-Assisted Sorbent Extraction

Capturing Actively Produced Microbial Volatile Organic Compounds from Human-Associated Samples with Vacuum-Assisted Sorbent Extraction

Published on: June 1, 2022

Related Experiment Videos

Last Updated: May 28, 2026

Tea Aroma Analysis Based on Solvent-Assisted Flavor Evaporation Enrichment

Tea Aroma Analysis Based on Solvent-Assisted Flavor Evaporation Enrichment

Published on: May 26, 2023

Profiling Volatile Compounds in Blackcurrant Fruit using Headspace Solid-Phase Microextraction Coupled to Gas Chromatography-Mass Spectrometry

Profiling Volatile Compounds in Blackcurrant Fruit using Headspace Solid-Phase Microextraction Coupled to Gas Chromatography-Mass Spectrometry

Published on: June 9, 2021

Capturing Actively Produced Microbial Volatile Organic Compounds from Human-Associated Samples with Vacuum-Assisted Sorbent Extraction

Capturing Actively Produced Microbial Volatile Organic Compounds from Human-Associated Samples with Vacuum-Assisted Sorbent Extraction

Published on: June 1, 2022

Area of Science:

Analytical Chemistry
Physical Chemistry
Colloid and Surface Chemistry

Background:

Understanding solute partitioning in micellar solutions is crucial for various chemical processes.
Sodium dodecyl sulfate (SDS) forms micelles that influence the solubility and distribution of hydrophobic compounds like limonene.
Headspace solid-phase microextraction (HS-SPME) is a sensitive technique for analyzing volatile compounds in aqueous systems.

Purpose of the Study:

To quantify the equilibrium partitioning of limonene between water and SDS micelles using HS-SPME.
To determine the partition coefficient and critical micelle concentration (CMC) of SDS for limonene.
To investigate the effect of limonene and SDS concentrations on partitioning behavior and micellar structure.

Main Methods:

Headspace solid-phase microextraction (HS-SPME) for sampling limonene vapor.
Gas chromatography/mass spectrometry (GC/MS) for quantifying limonene on the SPME fiber.
Mass balance calculations to determine partition coefficients and CMC from headspace concentrations.

Main Results:

HS-SPME effectively quantified limonene partitioning in SDS solutions.
A constant partition coefficient of 1700 M⁻¹ was observed at low limonene concentrations.
At higher limonene concentrations, the partition coefficient increased, suggesting micelle swelling and microemulsion formation.
The study observed the influence of SDS concentration on limonene's aqueous solubility limit.

Conclusions:

HS-SPME is a viable method for studying solute-micelle interactions.
Limonene partitioning is concentration-dependent, reflecting changes in micellar aggregation state.
The findings provide insights into the behavior of hydrophobic solutes in surfactant solutions.