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Selective binding and fluorescence sensing of diphosphate in H2O via Zn(2+)-induced allosteric regulation of the
Carla Bazzicalupi1, Andrea Bencini, Stefano Puccioni
1Dipartimento di Chimica Ugo Schiff, Università di Firenze, Via della Lastruccia 3, 50019-Sesto Fiorentino, Firenze, Italy.
Abstract:
A terpyridine-based receptor featuring two [9]aneN(3) units is able to selectively bind and sense diphosphate over mono- and triphosphate in aqueous solution at pH 7, thanks to the conformational change of its structure induced by Zn(2+) coordination to the polypyridyl moiety.
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