Related Experiment Video
Updated: May 27, 2026

Line Shape Analysis of Dynamic NMR Spectra for Characterizing Coordination Sphere Rearrangements at a Chiral Rhenium Polyhydride Complex
Published on: July 27, 2022
Dibromidooxido[(Z)-N'-(propan-2-yl-idene)benzohydrazidato](triphenyl-phosphane)rhenium(V)
Nonzaliseko Yumata1, Thomas Gerber, Richard Betz
1Nelson Mandela Metropolitan University, Summerstrand Campus, Department of Chemistry, University Way, Summerstrand, PO Box 77000, Port Elizabeth, 6031, South Africa.
Abstract:
The asymmetric unit of the title neutral rhenium(V) coordination compound, [ReBr(2)(C(10)H(11)N(2)O)O(C(18)H(15)P)], contains two mol-ecules. In each of the two molecules the metal atom is octa-hedrally coordinated, the bromido ligands being cis-orientated. The chelate ligand is present in its imine-tautomeric form. In the crystal, C-H⋯Br contacts connect the mol-ecules into chains along [101]. The shortest inter-centroid distance between two aromatic rings was found to be 3.906 (2) Å.
More Related Videos
10:51The Synthesis, Characterization and Reactivity of a Series of Ruthenium N-triphosPh Complexes
Published on: April 10, 2015
19:58Palladium N-Heterocyclic Carbene Complexes: Synthesis from Benzimidazolium Salts and Catalytic Activity in Carbon-carbon Bond-forming Reactions
Published on: July 30, 2017
Related Concept Videos
α-Bromination of Carboxylic Acids: Hell–Volhard–Zelinski Reaction
Formation of Halohydrin from Alkenes
Reactions at the Benzylic Position: Halogenation
Diazonium Group Substitution: –OH and –H
Electrophilic 1,2- and 1,4-Addition of X2 to 1,3-Butadiene
Hydrolysis of Chlorobenzene to Phenol: Dow Process