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Line Shape Analysis of Dynamic NMR Spectra for Characterizing Coordination Sphere Rearrangements at a Chiral Rhenium Polyhydride Complex
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Dual emission from rhenium(I) complexes induced by an interligand aromatic interaction

Tatsuki Morimoto1, Megumi Ito, Kazuhide Koike

  • 1Department of Chemistry, Graduate School of Science and Engineering, Tokyo Institute of Technology, 2-12-1-E1-9 O-okayama, Tokyo, 152-8551, Japan.

Chemistry (Weinheim an Der Bergstrasse, Germany)
|February 8, 2012
PubMed
Summary

The number of phenyl groups on phosphine ligands in rhenium(I) complexes controls π-π interactions, significantly altering electrochemical and photophysical properties. This structural control influences complex behavior and enables dual emission from conformers.

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