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Complexation between pillar[5]arenes and a secondary ammonium salt

Chengyou Han1, Guocan Yu, Bo Zheng

  • 1Department of Chemistry, Zhejiang University, Hangzhou 310027, P. R. China.

Organic Letters
|March 16, 2012
PubMed
Summary

We formed a [2]pseudorotaxane using n-octylethyl ammonium hexafluorophosphate threaded through 1,4-dimethoxypillar[5]arene. This supramolecular assembly, confirmed by NMR and mass spectrometry, can be reversibly switched off with chloride ions.

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