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Updated: May 23, 2026

Preparation of Enantiopure Non-Activated Aziridines and Synthesis of Biemamide B, D, and epiallo-Isomuscarine
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Published on: June 13, 2022

Introducing axial chirality into mesoionic 4,4'-bis(1,2,3-triazole) dicarbenes

Jesus M Aizpurua1, Maialen Sagartzazu-Aizpurua, Zaira Monasterio

  • 1Departamento de Química Orgánica-I, Universidad del País Vasco UPV/EHU, Joxe Mari Korta R&D Center, Avda Tolosa-72, 20018 San Sebastián, Spain. jesusmaria.aizpurua@ehu.es

Organic Letters
|March 22, 2012
PubMed
Summary

Chiral Rh(I) complexes with a C2 axis were synthesized from triazolium salts. These novel mesoionic compounds exhibit high configurational stability, confirmed by spectroscopy and crystallography, and involve a unique carbene intermediate.

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