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Updated: May 22, 2026

07:58
A Polyaniline-based Sensor of Nucleic Acids
Published on: November 1, 2016
Photodynamic ion sensor systems with spiropyran: photoactivated acidity changes in plasticized poly(vinyl chloride)
Günter Mistlberger1, Gastón A Crespo, Xiaojiang Xie
1University of Geneva, 30 Quai Ernest Ansermet, 1211 Geneva 4, Switzerland. g.mistlberger@gmail.com
Abstract:
We aim to introduce photoactivated optical ion sensors based on a triggered ion exchange process as novel dynamic tools. The quantification of the acidity change upon photoactivation of spiropyran within an organic membrane phase during photoexcitation is described here for the first time, suggesting a large pK(a) change of more than 6 orders of magnitude.

