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Development of Heterogeneous Enantioselective Catalysts using Chiral Metal-Organic Frameworks (MOFs)
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Published on: January 17, 2020

Helicity discrimination in diaryl dichalcogenides generated by inclusion complexation with chiral hosts

Teresa Olszewska1, Elżbieta Nowak, Maria Gdaniec

  • 1Department of Chemistry, Technical University , 80-233 Gdańsk, Poland, and Faculty of Chemistry, A. Mickiewicz University , 60-780 Poznań, Poland.

Organic Letters
|May 4, 2012
PubMed
Summary

Diaryl dichalcogenides can be distinguished by their helical properties when complexed with cholic acid or chiral diols. This inclusion complexation induces optical activity, measurable via solid-state circular dichroism (CD) spectroscopy.

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