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Cercosporin-Photocatalyzed [4+1]- and [4+2]-Annulations of Azoalkenes Under Mild Conditions
Published on: July 17, 2020
3-(3-Meth-oxy-benzyl-idene)chroman-4-one
Summary
The crystal structure of a C(17)H(14)O(3) compound reveals a specific dihedral angle between its aromatic rings. This molecular arrangement is primarily stabilized by weak intermolecular C-H⋯O interactions.
Area of Science:
- Crystallography
- Organic Chemistry
- Molecular Structure
Background:
- Understanding the three-dimensional arrangement of atoms in organic molecules is crucial.
- Chromanone derivatives are a class of compounds with diverse applications.
- Intermolecular forces play a significant role in crystal lattice stability.
Purpose of the Study:
- To determine the precise crystal structure of the title compound C(17)H(14)O(3).
- To quantify the dihedral angle between the methoxy-benzene unit and the chromanone system's benzene ring.
- To identify the key intermolecular interactions stabilizing the crystal.
Main Methods:
- Single-crystal X-ray diffraction analysis was employed.
- The crystal structure was solved and refined.
- Intermolecular interactions were analyzed using crystallographic data.
Main Results:
- The crystal structure of C(17)H(14)O(3) was successfully elucidated.
- A dihedral angle of 64.12(3)° was measured between the methoxy-benzene unit and the chromanone benzene ring.
- Weak C-H⋯O interactions were identified as the primary stabilizing forces in the crystal lattice.
Conclusions:
- The study provides detailed structural information for the C(17)H(14)O(3) compound.
- The observed dihedral angle offers insight into the molecule's conformation in the solid state.
- The findings highlight the importance of weak hydrogen bonds in stabilizing organic crystal structures.
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