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Updated: May 21, 2026

Preparation of Highly Porous Coordination Polymer Coatings on Macroporous Polymer Monoliths for Enhanced Enrichment of Phosphopeptides
Published on: July 14, 2015
Quest for highly porous metal-metalloporphyrin framework based upon a custom-designed octatopic porphyrin ligand
Xi-Sen Wang1, Matthew Chrzanowski, Chungsik Kim
1Department of Chemistry, University of South Florida, 4202 E. Fowler Avenue, Tampa, FL 33620, USA.
Abstract:
A porous metal-metalloporphyrin framework, MMPF-2, has been constructed from a custom-designed octatopic porphyrin ligand, tetrakis(3,5-dicarboxyphenyl)porphine, that links a distorted cobalt trigonal prism secondary building unit. MMPF-2 possesses permanent microporosity with the highest surface area of 2037 m(2) g(-1) among reported porphyrin-based MOFs, and demonstrates a high uptake capacity of 170 cm(3) g(-1) CO(2) at 273 K and 1 bar.
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