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Synthesis and biological evaluation of a new triazole-oxotechnetium complex

Olivier Martinage1, Loïc Le Clainche, Bertrand Czarny

  • 1CEA, iBiTecS, Service d'Ingénierie Moléculaire des Protéines, Laboratoire de Chimie du Vivant, bâtiment 152, 91191 Gif-sur-Yvette, France.

Organic & Biomolecular Chemistry
|July 4, 2012
PubMed

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The reaction of weakly electrophilic aryldiazonium (also called arenediazonium) salts with highly activated aromatic compounds leads to the formation of products with an —N=N— link, called an azo linkage. This reaction, presented in Figure 1, is known as diazo coupling and occurs without the loss of the nitrogen atoms of the aryldiazonium salt. Highly activated aromatic compounds such as phenols or arylamines favor the diazo coupling reaction. The coupling generally occurs at the para position.