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Updated: May 19, 2026
The Synthesis, Characterization and Reactivity of a Series of Ruthenium N-triphosPh Complexes
Published on: April 10, 2015
Synthesis and characterization of a metallapyridyne complex
Tongdao Wang1, Hong Zhang, Feifei Han
1Department of Chemistry, College of Chemistry and Chemical Engineering, and State Key Laboratory of Physical Chemistry of Solid Surfaces, Xiamen University, Xiamen, China.
Abstract:
Building bridges: The first m-metallapyridine and the first metallapyridyne were synthesized under mild reaction conditions. The two complexes are metal-bridged polycyclic metallabenzenoid aromatics, in which the transition-metal center is shared by both six-membered rings. The synthetic method permits the use of metallabenzene as a starting material to access higher π-electron metallaaromatics.
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