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Updated: May 18, 2026

Covalent Attachment of Single Molecules for AFM-based Force Spectroscopy
Published on: March 16, 2020
Exploring atomic-scale lateral forces in the attractive regime: a case study on graphite (0001).
Mehmet Z Baykara1, Todd C Schwendemann, Boris J Albers
1Department of Mechanical Engineering and Materials Science and Center for Research on Interface Structures and Phenomena (CRISP), Yale University, PO Box 208284, New Haven, CT 06520, USA. mehmet.baykara@bilkent.edu.tr
This study introduces a non-contact atomic force microscopy method to map lateral forces between a probe tip and graphite. Lateral forces linearly depend on normal force at small distances, offering insights into friction.
Area of Science:
- Surface science
- Nanotechnology
- Tribology
Background:
- Atomic force microscopy (AFM) is crucial for nanoscale surface analysis.
- Understanding tip-sample interactions is key to friction and adhesion studies.
- Previous methods faced limitations in resolution and contact area effects.
Purpose of the Study:
- To develop and demonstrate a non-contact AFM method for mapping lateral forces.
- To quantify lateral forces with high resolution.
- To analyze lateral forces as a function of tip position and distance.
Main Methods:
- Utilized non-contact atomic force microscopy (AFM).
- Employed an atomically sharp Platinum/Iridium (Pt/Ir) probe tip.
- Conducted measurements at low temperatures in the attractive regime.
Main Results:
- Successfully mapped static lateral forces between a Pt/Ir tip and graphite surface.
- Achieved piconewton force and picometer position resolution.
- Observed a linear relationship between lateral and normal forces at small tip-sample distances.
Conclusions:
- The non-contact AFM method provides unique insights into nanoscale lateral forces.
- The findings offer a new approach to study friction at the atomic level.
- Lateral forces in the attractive regime are directly related to normal forces for specific tip-sample geometries.
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