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"Hard-soft" synthesis of SrCrO3-δ superstructure phases

Angel M Arévalo-López1, Jennifer A Rodgers, Mark S Senn

  • 1Centre for Science at Extreme Conditions and School of Chemistry, University of Edinburgh, Mayfield Road, Edinburgh EH9 3JZ, UK.

Angewandte Chemie (International Ed. in English)
|September 27, 2012
PubMed
Abstract

No abstract available in PubMed .

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Chirality is most prevalent in carbon-based tetrahedral compounds, but this important facet of molecular symmetry extends to sp3-hybridized nitrogen, phosphorus and sulfur centers, including trivalent molecules with lone pairs. Here, the lone pair behaves as a functional group in addition to the other three substituents to form an analogous tetrahedral center that can be chiral.
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