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Updated: May 17, 2026

Preparation of Biomass-based Mesoporous Carbon with Higher Nitrogen-/Oxygen-chelating Adsorption for Cu(II) Through Microwave Pre-Pyrolysis
Published on: February 12, 2019
Gate adsorption of CO2 on a flexible one-dimensional copper-based coordination polymer crystal
Ryosuke Kotani1, Atsushi Kondo, Kazuyuki Maeda
1Department of Applied Chemistry, Faculty of Engineering, Tokyo University of Agriculture and Technology, 2-24-16 Naka-cho, Koganei, Tokyo 184-8588, Japan.
Abstract:
A flexible one-dimensional copper-based coordination polymer (CP) crystal was synthesized and the crystal structure was solved. This CP crystal shows a single step gate adsorption uptake of CO(2) under moderate conditions (268 K ≤ T ≤ 303 K, P < 1 atm) irrespective of no N(2) uptake at 77 K.
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To explain the observed behavior of transition metal complexes (such as colors), a model involving electrostatic interactions between the electrons from the ligands and the electrons in the unhybridized d orbitals of the central metal atom has been developed. This electrostatic model is crystal field theory (CFT). It helps to understand, interpret, and predict the colors, magnetic behavior, and some structures of coordination compounds of transition metals.
CFT focuses on...