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Nitroso-dienophile additions to dendralenes: a short synthesis of branched aminosugars

Ruomeng Wang1, Gomotsang Bojase, Anthony C Willis

  • 1Australian Research Council Centre of Excellence for Free Radical Chemistry and Biotechnology, Research School of Chemistry, Australian National University, Canberra, ACT 0200, Australia.

Organic Letters
|October 31, 2012
PubMed

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Characteristics of the diene
Conformation
The simplest example of a diene is 1,3-butadiene, an acyclic conjugated π system. At room temperature, the molecule exists as a mixture of s-cis and s-trans conformers by virtue of rotation around the carbon–carbon single bond. Although the s-trans isomer is more stable, the...
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