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Updated: May 16, 2026

Fabrication and Optimization of Type II Silicon Clathrate Films
Published on: October 14, 2025
A mechanochemically synthesised solid solution enables engineering of the sorption properties of a Werner clathrate
Eustina Batisai1, Matteo Lusi, Tia Jacobs
1Department of Chemistry and Polymer Science, University of Stellenbosch, Stellenbosch, 7600, South Africa.
Abstract:
Mechanochemical synthesis has been used to obtain two Werner complexes and their solid solution that could not be obtained by conventional "wet" chemistry; remarkably, despite the structural and chemical similarity, the solid solution exhibits sorption properties that differ from those of the pure compounds.
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