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Updated: May 16, 2026

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Potentiodynamic Corrosion Testing
Published on: September 4, 2016
CoCrMo metal-on-metal hip replacements.
Yifeng Liao1, Emily Hoffman, Markus Wimmer
1Department of Materials Science and Engineering, Northwestern University, Evanston, IL, USA.
Physical Chemistry Chemical Physics : PCCP
|December 1, 2012
Summary
Metal-on-metal hip implants face scrutiny due to wear and corrosion. Understanding these CoCrMo implant interactions is crucial for patient safety and improved joint replacement design.
Area of Science:
- Biomaterials Science
- Orthopedic Surgery
- Tribology
Background:
- Metal-on-metal hip replacements (CoCrMo) saw increased use but declined due to biocompatibility concerns.
- Wear and corrosion debris from these implants raise significant concerns about local tissue response.
- The in vivo and in vitro interactions between CoCrMo bearings and the human body remain poorly understood.
Purpose of the Study:
- To review recent advancements in understanding the wear and corrosion of metal-on-metal hip replacements.
- To discuss key factors influencing implant performance, including materials, deformation, and tribocorrosion.
- To highlight open questions and potential adverse health effects associated with implant wear products.
Main Methods:
- Review of in vivo and in vitro studies on CoCrMo hip implant wear and corrosion.
- Discussion of material properties, mechanical deformation, and electrochemical corrosion processes.
- Analysis of wear-assisted corrosion mechanisms and the characterization of wear products.
Main Results:
- CoCrMo metal-on-metal hip implants generate wear and corrosion debris.
- These debris particles can elicit adverse local tissue reactions.
- The complex chemistry of corrosion and tribochemical reactions requires further investigation.
Conclusions:
- Further research is needed to fully elucidate the chemistry of corrosion and tribochemical reactions in CoCrMo hip implants.
- Understanding these interactions is vital for improving the safety and longevity of artificial hip joints.
- Designing advanced materials for human implants requires similar attention to performance as seen in automotive applications.

