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Accessing Valuable Ligand Supports for Transition Metals: A Modified, Intermediate Scale Preparation of 1,2,3,4,5-Pentamethylcyclopentadiene
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Published on: March 20, 2017

A simple metal-promoted three-step access to n/5/m angular carbocyclic systems

José Barluenga1, Ana Álvarez-Fernández, Tatiana Suárez-Rodríguez

  • 1Departamento de Química Orgánica e Inorgánica, Universidad de Oviedo, Julian Clavería 8, 33071 Oviedo, Spain. barluenga@uniovi.es

Organic Letters
|January 12, 2013
PubMed
Summary

A new three-step synthesis provides access to angular tricyclic skeletons using readily available starting materials. This method utilizes cyclopentannulation and metal-promoted fragmentation, followed by cyclization strategies.

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