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Self-assembling Morphologies Obtained from Helical Polycarbodiimide Copolymers and Their Triazole Derivatives
Published on: February 7, 2017
Shape-persistent H-bonded macrocyclic aromatic pentamers.
Haoliang Fu1, Ying Liu, Huaqiang Zeng
1Faculty of Chemical Engineering and Light Industry, Guang Dong University of Technology, Guang Dong, 510006, China.
Chemical Communications (Cambridge, England)
|January 16, 2013
Summary
Multiple-center intramolecular hydrogen bonds enable efficient synthesis of diverse macrocycles. These shape-persistent macrocyclic foldamers create tunable cavities and tailor-made functions, expanding research dimensions.
Area of Science:
- Supramolecular Chemistry
- Organic Synthesis
- Materials Science
Background:
- Macrocycle synthesis is crucial for developing new materials and molecular tools.
- Traditional methods often face limitations in structural diversity and functional control.
- Intramolecular hydrogen bonding offers a novel approach to macrocyclic construction.
Purpose of the Study:
- To highlight recent advances in macrocycle synthesis using multiple-center intramolecular hydrogen bonds.
- To showcase the design, synthesis, structure, and function of shape-persistent macrocyclic foldamers.
- To demonstrate the expansion of structural and functional possibilities in macrocyclic chemistry.
Main Methods:
- Utilizing multiple-center intramolecular hydrogen bonds for macrocycle construction.
- Designing and synthesizing novel macrocyclic foldamers.
- Characterizing the structural properties, including cavity size (2.8 Å to 15 Å radius).
- Evaluating the tailored functions of the synthesized macrocycles.
Main Results:
- Efficient construction of macrocycles with diverse structures and functions.
- Creation of macrocycles with tunable interior cavities.
- Demonstration of tailor-made functions in several synthesized macrocycles.
- Development of shape-persistent macrocyclic foldamers.
Conclusions:
- Multiple-center intramolecular hydrogen bonds represent a powerful strategy for macrocycle synthesis.
- This approach significantly expands the repertoire of shape-persistent macrocycles.
- The resulting macrocycles offer new dimensions for scientific research and applications.
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