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Updated: May 14, 2026

Facile Preparation of (2Z,4E)-Dienamides by the Olefination of Electron-deficient Alkenes with Allyl Acetate
Published on: June 21, 2017
Green diacetoxylation of alkenes in a microchemical system
Jeong Hyeon Park1, Chan Yi Park, Hyun Seung Song
1Graduate School of Analytical Science and Technology (GRAST), Chungnam National University, Daejeon 305-764, Korea.
Abstract:
The palladium-catalyzed diacetoxylation and trifluoromethanesulfonic acid-catalyzed diacetoxylation using inexpensive and environmentally friendly hydrogen peroxide and peracetic acid were successfully conducted with the help of microchemical technology. Excellent yield and selectivity were achieved in significantly shortened reaction times without the decomposition of explosive oxidants and further transformation of unstable products, offering a safe and efficient alternative to traditional methods for alkene diacetoxylation.
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