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Updated: May 13, 2026

Synthesis and Characterization of Functionalized Metal-organic Frameworks
Published on: September 5, 2014
Bis(trimethyl-phenyl-ammonium) μ-oxalato-bis-[oxidodiperoxido-molybdate(VI)]
1Department of Material Science and Chemistry, Faculty of Systems Engineering, Wakayama University, Sakaedani 930, Wakayama 640-8510, Japan.
Abstract:
A trimethyl-phenyl-ammonium salt of a dinuclear μ-oxalate complex of diperoxidomonomolybdate units, (C9H14N)2[Mo2(C2O4)(O2)4O2], was obtained from an acidic aqueous solution; the dianion is located about a centre of inversion. Each Mo atom bears two peroxide groups together with one O atom from the oxalate group in its equatorial positions and one terminal O atom as well as another O atom from the oxalate in axial positions. The oxalate group acts as a tetra-dentate bridging ligand and bridges between the diperoxidomolybdate units.
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