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Updated: May 13, 2026
![Mizoroki-Heck Cross-coupling Reactions Catalyzed by Dichloro{bis[1,1',1''-(phosphinetriyl)tripiperidine]}palladium Under Mild Reaction Conditions](/_next/image?url=https%3A%2F%2Fcloudfront.jove.com%2FCDNSource%2Fteasers%2F51444.jpg&w=3840&q=50)
Mizoroki-Heck Cross-coupling Reactions Catalyzed by Dichloro{bis[1,1',1''-(phosphinetriyl)tripiperidine]}palladium Under Mild Reaction Conditions
Published on: March 20, 2014
Di-μ-iodido-bis-[(biphenyl-2-yl)(triphenyl-phosphane-κP)palladium(II)]
1Department of Chemistry, Central Connecticut State University, New Britain, CT 06053, USA.
Abstract:
In the title compound, [Pd2(C12H9)2I2(C18H15P)2], the dimeric complex mol-ecule lies about an inversion center. The Pd⋯I⋯Pd bridges are slightly asymmetric, with Pd-I distances of 2.6709 (6) and 2.7486 (7) Å. The metal atom has a slightly puckered square-planar CI2P environment, the largest deviation from the least-squares plane being 0.143 (8) Å.
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