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Updated: May 11, 2026

Preparation of Stable Bicyclic Aziridinium Ions and Their Ring-Opening for the Synthesis of Azaheterocycles
Published on: August 22, 2018
Total synthesis of (8R,6'R)-peridinin-5,8-furanoxide
Leticia Otero1, Belén Vaz, Rosana Álvarez
1Department of Organic Chemistry As Lagoas-Marcosende, Universidade de Vigo, 36315 Vigo, Spain.
Abstract:
The first total synthesis of (8R,6'R)-peridinin-5,8-furanoxide, a C37 xanthophyll norcarotenoid, has been achieved. The key steps of the synthetic sequence are a Julia-Kocienski condensation and a late stage stereoretentive Stille cross-coupling of an iodoallene.
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