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Roxbin B is cuspinin: structural revision and total synthesis

Sayuri Yamaguchi1, Tsukasa Hirokane, Takashi Yoshida

  • 1School of Science and Technology, Kwansei Gakuin University, 2-1 Gakuen, Sanda 669-1337, Japan.

The Journal of Organic Chemistry
|May 10, 2013
PubMed
Summary

Roxbin B, initially synthesized and found different from its natural form, was re-examined. Structural analysis and total synthesis confirmed Roxbin B is identical to cuspinin, a rare natural product with (R)-axial chirality.

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