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Cercosporin-Photocatalyzed [4+1]- and [4+2]-Annulations of Azoalkenes Under Mild Conditions
Published on: July 17, 2020
2-(4-Hy-droxy-phen-yl)-3-meth-oxy-4H-chromen-4-one
Illia E Serdiuk1, Michał Wera, Alexander D Roshal
1Institute of Chemistry, V.N. Karazin National University, Svobody 4, 61077 Kharkiv, Ukraine ; Faculty of Chemistry, University of Gdańsk, J. Sobieskiego 18, 80-952 Gdańsk, Poland.
Abstract:
In the title compound, C16H12O4, the substituent benzene ring and meth-oxy group are twisted relative to the 4H-chromene skeleton by 24.1 (1) and 61.3 (1)°, respectively. In the crystal, mol-ecules are connected by classical O-H⋯O and weak C-H⋯O hydrogen bonds, forming chains parallel to [201]. The 4H-chromene ring systems of adjacent mol-ecules are either parallel or inclined at an angle of 28.9 (1)°.
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