Room temperature C-H bond activation on a [Pd(I)-Pd(I)] platform
Mithun Sarkar1, Henri Doucet, Jitendra K Bera
1Department of Chemistry, Indian Institute of Technology Kanpur, Kanpur 208016, India. jbera@iitk.ac.in.
Abstract:
Heteroatom assisted C-H bond activation of 2-substituted naphthyridines with solvated Pd(I)2(CH3CN)6(BF4)2 provides bi- and trinuclear Pd(II) cyclometalated complexes, which provide valuable insight into potential intermediates in palladium catalyzed direct arylation reactions.
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