Reactions between aqueous zinc, aluminium and iron with increasing solutionpH

Solutions of zinc, aluminium and/or iron, as chlorides in NaCl of ionic strength 0.13 mol/l atpH 3, were mixed to give initial concentrations of 0-5, 5-50 and 10-100 μg/ml, respectively. Sodium hydroxide was then added to increase thepH in a range up to 7. Turbidity was measured and equilibrium concentrations were determined after filtration (< 0.1 μm). Decrease inpH on mixing suggested an immediate reaction, with the release of protons. At allpH values Zn concentration decreased with increasing initiai concentrations of Fe and Al. Adsorption and/or nucleation of Zn with Fe and Al was highlypH dependent and increased markediy with increasingpH. The particle size of the products increased with increasingpH and initial concentration of the elements. Increasing Al concentration decreased the size of Fe nucleates at a given Fe concentration. The results suggest that co-precipitation may be involved as well as adsorption. This has important consequences for the availability of Zn to plants, especially in Zn-deficient soils, and is of relevance to the products of mixing acid drainage waters with streams and lakes.