A microvascular system for chemical reactions using surface waste heat
Du Thai Nguyen1, Aaron P Esser-Kahn
1Dept. of Physics and Astronomy, University of California, Irvine, 3038A Frederick Reines Hall, Irvine, CA 92697 (USA).
Angewandte Chemie (International Ed. in English)
|December 6, 2013
Summary
Waste heat from surfaces can power chemical reactions, like regenerating carbon dioxide (CO2) capture solutions. This technology uses microchannels, even in everyday items like a coffee mug, for efficient CO2 removal.
Area of Science:
- Chemical Engineering
- Materials Science
- Thermodynamics
Background:
- Low-grade waste heat is an abundant but underutilized energy source.
- Carbon capture technologies require energy for solution regeneration.
- Microvascular systems offer efficient heat and mass transfer capabilities.
Purpose of the Study:
- To demonstrate the use of low-grade waste heat for chemical reactions.
- To explore the application of flowing two-phase heat transfer in microvascular systems for CO2 capture.
- To adapt microchannel technology to pre-fabricated surfaces.
Main Methods:
- Implementing flowing two-phase heat transfer within microvascular systems.
- Utilizing waste heat from surfaces to drive chemical reactions.
- Integrating a microchannel (1.2 m long) into a coffee mug for CO2 stripping.
Main Results:
- Successful regeneration of a monoethanolamine (MEA) CO2 capture solution using low-grade waste heat.
- Demonstration of heat transfer within a microchannel integrated into a coffee mug.
- Feasibility of adapting microvascular heat transfer systems to existing surfaces.
Conclusions:
- Low-grade waste heat can effectively drive chemical processes like CO2 capture regeneration.
- Microvascular systems integrated into everyday objects are a viable approach for energy-efficient chemical applications.
- This technology offers a novel pathway for waste heat recovery and CO2 mitigation.
Related Concept Videos
Thermal and Photochemical Electrocyclic Reactions: Overview
2.1K
Electrocyclic reactions are reversible reactions. They involve an intramolecular cyclization or ring-opening of a conjugated polyene. Shown below are two examples of electrocyclic reactions. In the first reaction, the formation of the cyclic product is favored. In contrast, in the second reaction, ring-opening is favored due to the high ring strain associated with cyclobutene formation.
2.1K
Chemical Reactions
81.9K
A chemical reaction is a process by which the bonds in the atoms of substances are rearranged to generate new substances. Matter cannot be created or destroyed in a chemical reaction—the same type and number of atoms that make up the reactants are still present in the products. Merely, the rearrangement of chemical bonds produces new compounds.
Chemical Reactions Rearrange Atoms into New Substances
A chemical reaction takes starting materials—the reactants—and changes them...
Chemical Reactions Rearrange Atoms into New Substances
A chemical reaction takes starting materials—the reactants—and changes them...
81.9K
Thermal Sigmatropic Reactions: Overview
1.6K
Sigmatropic rearrangements are a class of pericyclic reactions in which a σ bond migrates from one part of a π system to another. These are intramolecular rearrangements where the total number of σ and π bonds remain unchanged.
Sigmatropic shifts are classified based on an order term [i, j ], where i and j indicate the number of atoms across which each end of the σ bond migrates. Below are examples of a [3,3] sigmatropic shift in...
Sigmatropic shifts are classified based on an order term [i, j ], where i and j indicate the number of atoms across which each end of the σ bond migrates. Below are examples of a [3,3] sigmatropic shift in...
1.6K
Mechanisms of Heat Transfer II
4.5K
In convection, thermal energy is carried by the large-scale flow of matter. Ocean currents and large-scale atmospheric circulation, which result from the buoyancy of warm air and water, transfer hot air from the tropics toward the poles and cold air from the poles toward the tropics. The Earth’s rotation interacts with those flows, causing the observed eastward flow of air in the temperate zones. Convection dominates heat transfer by air, and the amount of available space for the airflow...
4.5K
Electrochemical Systems
179
Electrochemical systems provide a fascinating insight into the dynamic interplay of charged species within various phases. One notable example is the interaction between a membrane permeable to K⁺ ions but not to Cl⁻ ions, separating an aqueous KCl solution from pure water. As K⁺ ions diffuse through the membrane, they generate net charges on each phase, leading to a potential difference between them.Similarly, when a piece of Zn is immersed in an aqueous ZnSO₄ solution,...
179


