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Updated: May 3, 2026

A Two-Step Protocol for Umpolung Functionalization of Ketones Via Enolonium Species
Published on: August 16, 2018
2-(3,4-Di-meth-oxy-phen-yl)-1-pentyl-4,5-diphenyl-1H-imidazole
Shaaban K Mohamed1, Mehmet Akkurt2, Adel A Marzouk3
1Chemistry and Environmental Division, Manchester Metropolitan University, Manchester M1 5GD, England ; Chemistry Department, Faculty of Science, Minia University, 61519 El-Minia, Egypt.
Abstract:
The central imidazole ring in the title compound, C28H30N2O2, makes dihedral angles of 28.42 (13), 71.22 (15) and 29.50 (14)°, respectively, with the phenyl rings in the 4- and 5-positions and the 3,4-di-meth-oxy-phenyl group. In the crystal, mol-ecules are linked by C-H⋯O and C-H⋯N hydrogen bonds, weak π-π stacking inter-actions [centroid-centroid distance = 3.760 (2) Å] and C-H⋯π contacts, forming a three-dimensional network.
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