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Updated: May 3, 2026

Activating Molecules, Ions, and Solid Particles with Acoustic Cavitation
Published on: April 11, 2014
Energy balance for a sonoluminescence bubble yields a measure of ionization potential lowering
B Kappus1, A Bataller1, S J Putterman2
1Department of Physics and Astronomy, University of California, Los Angeles, California 90095, USA.
Abstract:
Application of energy conservation between input sound and the microplasma which forms at the moment of sonoluminescence places bounds on the process, whereby the gas is ionized. Detailed pulsed Mie scattering measurements of the radius versus time for a xenon bubble in sulfuric acid provide a complete characterization of the hydrodynamics and minimum radius. For a range of emission intensities, the blackbody spectrum emitted during collapse matches the minimum bubble radius, implying opaque conditions are attained. This requires a degree of ionization >36%. Analysis reveals only 2.1±0.6 eV/atom of energy available during light emission. In order to unbind enough charge, collective processes must therefore reduce the ionization potential by at least 75%. We interpret this as evidence that a phase transition to a highly ionized plasma is occurring during sonoluminescence.
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