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Nuclear Transmutation03:20

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Nuclear transmutation is the conversion of one nuclide into another. It can occur by the radioactive decay of a nucleus, or the reaction of a nucleus with another particle. The first manmade nucleus was produced in Ernest Rutherford’s laboratory in 1919 by a transmutation reaction, the bombardment of one type of nuclei with other nuclei or with neutrons. Rutherford bombarded nitrogen-14 atoms with high-speed α particles from a natural radioactive isotope of radium and observed...
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Protons and neutrons, collectively called nucleons, are packed together tightly in a nucleus. With a radius of about 10−15 meters, a nucleus is quite small compared to the radius of the entire atom, which is about 10−10 meters. Nuclei are extremely dense compared to bulk matter, averaging 1.8 × 1014 grams per cubic centimeter. If the earth’s density were equal to the average nuclear density, the earth’s radius would be only about 200 meters.
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Microorganisms play a critical role in the transformation and immobilization of uranium in contaminated environments through four main pathways: bioreduction, biosorption, bioaccumulation, and biomineralization. These mechanisms reduce uranium’s toxicity and prevent its migration through groundwater systems, offering sustainable approaches for in situ bioremediation.Bioreduction of UraniumBioreduction is driven by anaerobic bacteria such as certain strains of Geobacter and Shewanella,...
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Nuclear chemistry is the study of reactions that involve changes in nuclear structure. The nucleus of an atom is composed of protons and, except for hydrogen, neutrons. The number of protons in the nucleus is called the atomic number (Z) of the element, and the sum of the number of protons and the number of neutrons is the mass number (A). Atoms with the same atomic number but different mass numbers are isotopes of the same element.
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Valence Bond Theory02:42

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Coordination compounds and complexes exhibit different colors, geometries, and magnetic behavior, depending on the metal atom/ion and ligands from which they are composed. In an attempt to explain the bonding and structure of coordination complexes, Linus Pauling proposed the valence bond theory, or VBT, using the concepts of hybridization and the overlapping of the atomic orbitals. According to VBT, the central metal atom or ion (Lewis acid) hybridizes to provide empty orbitals of suitable...
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In the early 1900s, English chemist Frederick Soddy realized that an element could have atoms with different masses that were chemically indistinguishable. These different types are called isotopes — atoms of the same element that differ in mass. Isotopes differ in mass because they have different numbers of neutrons but are chemically identical because they have the same number of protons. Soddy was awarded the Nobel Prize in Chemistry in 1921 for this discovery.
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Related Experiment Video

Updated: May 3, 2026

Removal of Trace Elements by Cupric Oxide Nanoparticles from Uranium In Situ Recovery Bleed Water and Its Effect on Cell Viability
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Removal of Trace Elements by Cupric Oxide Nanoparticles from Uranium In Situ Recovery Bleed Water and Its Effect on Cell Viability

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Nickel(II) uranium(IV) tris-ulfide.

Matthew D Ward1, James A Ibers1

  • 1Department of Chemistry, Northwestern University, 2145 Sheridan Rd, Evanston, IL 60208-3113, USA.

Acta Crystallographica. Section E, Structure Reports Online
|February 15, 2014
PubMed
Summary
This summary is machine-generated.

Researchers synthesized Nickel(II) uranium(IV) tris-ulfide (NiUS3) crystals. This new material exhibits an orthorhombic perovskite-like structure with unique uranium and nickel coordination environments.

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Area of Science:

  • Solid-state chemistry
  • Inorganic materials science
  • Crystallography

Background:

  • The synthesis of novel ternary transition metal sulfides is crucial for exploring new material properties.
  • Understanding crystal structures provides insights into chemical bonding and potential applications.

Purpose of the Study:

  • To synthesize and characterize a new ternary compound containing nickel, uranium, and sulfur.
  • To determine the crystal structure and coordination environments of NiUS3.

Main Methods:

  • Single crystal growth using a CsCl flux method at 1173 K.
  • X-ray diffraction analysis to determine crystal symmetry and structure.
  • Analysis of atomic coordination and site symmetry.

Main Results:

  • Crystals of Nickel(II) uranium(IV) tris-ulfide (NiUS3) were successfully synthesized.
  • NiUS3 crystallizes in the orthorhombic Pnma space group, adopting the GdFeO3 structure type.
  • The structure features a perovskite-like arrangement with uranium atoms in interstitial sites within a NiS6 framework, exhibiting distorted bicapped trigonal-prismatic and octahedral coordination for U and Ni, respectively.

Conclusions:

  • The successful synthesis and structural elucidation of NiUS3 expand the known family of ternary transition metal sulfides.
  • The observed perovskite-like structure and coordination geometries offer a foundation for further investigations into its physical and chemical properties.