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Plasma modified MoS(2) nanoflakes for surface enhanced raman scattering.
Linfeng Sun1, Hailong Hu, Da Zhan
1Division of Physics and Applied Physics, School of Physical and Mathematical Sciences, Nanyang Technological University, 637371, Singapore.
Small (Weinheim an Der Bergstrasse, Germany)
|February 18, 2014
Summary
Plasma treated molybdenum disulfide (MoS2) nanoflakes show enhanced Raman scattering signals. Structural disorder and oxygen adsorption are key factors driving this surface-enhanced Raman scattering (SERS) effect.
Area of Science:
- Materials Science
- Surface Chemistry
- Spectroscopy
Background:
- Pristine molybdenum disulfide (MoS2) exhibits limited utility as a substrate for surface-enhanced Raman scattering (SERS).
- Investigating novel materials for enhanced SERS detection is crucial for various analytical applications.
Purpose of the Study:
- To demonstrate the efficacy of plasma-treated MoS2 nanoflakes as a SERS substrate.
- To elucidate the underlying mechanisms responsible for the enhanced Raman scattering signals.
Main Methods:
- Fabrication of MoS2 nanoflakes.
- Plasma treatment of MoS2 nanoflakes.
- Characterization of treated nanoflakes using spectroscopy.
- Adsorption of R6G molecules onto the MoS2 substrate.
- Surface-enhanced Raman scattering (SERS) measurements.
Main Results:
- Plasma treatment significantly enhances the SERS activity of MoS2 nanoflakes.
- Structural disorder in plasma-treated MoS2 induces local dipoles, contributing to SERS enhancement.
- Adsorption of oxygen onto the MoS2 surface is another critical factor for signal amplification.
- Enhanced Raman signals were observed for surface-adsorbed R6G molecules.
Conclusions:
- Plasma-treated MoS2 nanoflakes are effective substrates for SERS.
- The enhanced SERS effect is attributed to plasma-induced structural disorder and oxygen adsorption.
- This study highlights a promising approach for developing advanced SERS substrates.

