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Microscopic origin of the surface tension anomaly of water
Marcello Sega1, George Horvai, Pál Jedlovszky
1Department of Physics, University of Rome "Tor Vergata" , Rome, Italy.
Abstract:
We investigate the hydrogen bonding percolation threshold of water molecules at the surface of the liquid-vapor interface. We show that the percolation temperature agrees within statistical accuracy with the high-temperature inflection point of the water surface tension. We associate the origin of this surface tension anomaly of water with the sudden breakup of the hydrogen-bonding network in the interfacial molecular layer.
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