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Synthesis of Bimetallic Pt/Sn-based Nanoparticles in Ionic Liquids
Published on: August 23, 2018
Bis(2,2'-bipyridyl-κ(2) N,N')chloridonickel(II) nitrate trihydrate
Mehdi Boutebdja1, Adel Beghidja1, Chahrazed Beghidja1
1Unité de Recherche de Chimie de l'Environnement et Moléculaire Structurale, (CHEMS), Faculté des Sciences Exactes, Département de Chimie, Université de Constantine 1, 25000 Constantine, Algeria.
Abstract:
In the title hydrated salt, [NiCl(C10H8N2)2](NO3)·3H2O, the Ni(2+) ion is coordinated by two 2,2'-bipyridyl (2,2'-bpy) ligands and a chloride ion in a trigonal-bipyramidal geometry. The chloride ion occupies an equatorial site and the dihedral angle between the 2,2'-bpy ring systems is 72.02 (6)°. In the crystal, the components are linked by C-H⋯O and O-H⋯O hydrogen bonds and aromatic π-π stacking inter-actions [shortest centroid-centroid separation = 3.635 (2) Å], generating a three-dimensional network.
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