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Covalently crosslinked fly ash/poly(acrylic acid-co-acrylamide) composite microgels as novel magnetic selective
1State Key Laboratory of Applied Organic Chemistry and Institute of Polymer Science and Engineering, College of Chemistry and Chemical Engineering, Lanzhou University, Lanzhou 730000, China; Chemical Department, Lanzhou University of Arts and Science, Lanzhou 730000, China.
Abstract:
In order to improve the performance of treating waste-water with wastes, the magnetic fly ash (FA) particles were surface-modified with polymerizable groups as the crosslinker for the copolymerization with acrylic acid (AA) and acrylamide (AM) by a facile inverse suspension polymerization process, without any foreign organic crosslinker added. The optimized beadlike magnetic fly ash/poly(acrylic acid-co-acrylamide) composite microgels (FA/P(AA-AM)) with 3-dimensional crosslinking skeleton structure were selected as the magnetic selective microgel adsorbent for Pb(2+) ion, through a series of L(9)(3(4)) orthogonal experiments. It was found that the magnetic FA particles could improve the strength stability of the FA/P(AA-AM) composite microgels, also provide the ability of magnetic separation.
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