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Related Experiment Videos

Cs3ScCl6.

Matthew D Ward1, James A Ibers1

  • 1Department of Chemistry, Northwestern University, 2145 Sheridan Rd, Evanston, IL 60208-3113, USA.

Acta Crystallographica. Section E, Structure Reports Online
|June 19, 2014
PubMed
Summary
This summary is machine-generated.

Tricaesium scandium(III) hexachloride (Cs3ScCl6) crystals were synthesized. This compound features isolated scandium hexachloro octahedra surrounded by cesium cations.

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Area of Science:

  • Inorganic Chemistry
  • Solid-State Chemistry
  • Crystallography

Background:

  • Scandium compounds are of interest due to their unique chemical properties.
  • High-temperature flux synthesis is a common method for obtaining novel inorganic materials.
  • Understanding crystal structures provides insights into chemical bonding and material properties.

Purpose of the Study:

  • To synthesize and characterize tricaesium scandium(III) hexachloride (Cs3ScCl6).
  • To determine the crystal structure of Cs3ScCl6.
  • To investigate the coordination environment of scandium and cesium ions.

Main Methods:

  • Single-crystal X-ray diffraction was used to determine the crystal structure.
  • High-temperature synthesis in a cesium chloride (CsCl) flux was employed.

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  • Chemical reactions involved uranium (U), tin(II) chloride (SnCl2), scandium (Sc), and sulfur (S).

    • Main Results:

    • Tricaesium scandium(III) hexachloride (Cs3ScCl6) was obtained as a byproduct.
    • The compound crystallizes in the Rb3YCl6 structure type.
    • The structure consists of isolated [ScCl6](3-) octahedra coordinated by Cs(+) cations.

    Conclusions:

    • Cs3ScCl6 represents a new crystalline phase.
    • The crystal structure reveals a unique arrangement of isolated octahedra and cations.
    • The coordination numbers of cesium cations vary, influencing the overall structure.