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Updated: Apr 27, 2026

Measurement of Ultrafast Vibrational Coherences in Polyatomic Radical Cations with Strong-Field Adiabatic Ionization
Published on: August 6, 2018
Strong-field dissociative double ionization of acetylene
Xiaochun Gong1, Qiying Song1, Qinying Ji1
1State Key Laboratory of Precision Spectroscopy, East China Normal University, Shanghai 200062, China.
Abstract:
We investigate dissociative double ionization of acetylene, one of the smallest organic molecules yet with a rich electronic structure, in strong laser fields by measuring two fragment ions and two electrons in coincidence. The two-body fragmentation channels are dominated by the removal of electrons from the lower-lying molecular orbitals rather than from the highest occupied one. The electron localization-assisted enhanced ionization mechanism plays a central role for the strong-field deprotonation ionization of acetylene by releasing the second electron from the up-field potential well of the hydrogen site at the internuclear distance near twice the equilibrium value of the C-H bond.
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