Crystallization kinetics of colloidal model suspensions: recent achievements and new perspectives

Colloidal model systems allow studying crystallization kinetics under fairly ideal conditions, with rather well-characterized pair interactions and minimized external influences. In complementary approaches experiment, analytic theory and simulation have been employed to study colloidal solidification in great detail. These studies were based on advanced optical methods, careful system characterization and sophisticated numerical methods. Over the last decade, both the effects of the type, strength and range of the pair-interaction between the colloidal particles and those of the colloid-specific polydispersity have been addressed in a quantitative way. Key parameters of crystallization have been derived and compared to those of metal systems. These systematic investigations significantly contributed to an enhanced understanding of the crystallization processes in general. Further, new fundamental questions have arisen and (partially) been solved over the last decade: including, for example, a two-step nucleation mechanism in homogeneous nucleation, choice of the crystallization pathway, or the subtle interplay of boundary conditions in heterogeneous nucleation. On the other hand, via the application of both gradients and external fields the competition between different nucleation and growth modes can be controlled and the resulting microstructure be influenced. The present review attempts to cover the interesting developments that have occurred since the turn of the millennium and to identify important novel trends, with particular focus on experimental aspects.