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Updated: Apr 26, 2026
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Structure and Coordination Determination of Peptide-metal Complexes Using 1D and 2D 1H NMR
Published on: December 16, 2013
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Stepwise assembly of an adamantoid Ru₄Ag₆ cage by control of metal coordination geometry at specific sites
Alexander J Metherell1, Michael D Ward
1Department of Chemistry, University of Sheffield, Sheffield S3 7HF, UK. m.d.ward@sheffield.ac.uk.
Chemical Communications (Cambridge, England)
|August 7, 2014
Abstract:
The geometrically pure 'complex ligand' fac-[Ru(L(ph))3](2+), in which three pendant bidentate binding sites are located on one face of the complex, reacts with Ag(I) ions to form the adamantoid decanuclear cage [{Ru(L(ph))3}4Ag6](PF6)14 which contains a 6-coordinate Ru(II) ion at each vertex of a large tetrahedron and a 4-coordinate Ag(I) ion along each edge.
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