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Electrophoretic Crystallization of Ultrathin High-performance Metal-organic Framework Membranes
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Dynamic response of ultrathin highly dense ZIF-8 nanofilms
Joanna Cookney1, Wojciech Ogieglo, Pavel Hrabanek
1Inorganic Membranes, Department of Science and Technology, Mesa+ Institute for Nanotechnology, University of Twente, P.O. Box 217, 7500 AE Enschede, The Netherlands. n.e.benes@utwente.nl.
Chemical Communications (Cambridge, England)
|August 22, 2014
Abstract:
Ultrathin ZIF-8 nanofilms are prepared by facile step-by-step dip coating. A critical withdrawal speed allows for films with a very uniform minimum thickness. The high refractive index of the films denotes the absence of mesopores. The dynamic response of the films to CO2 exposure resembles behaviour observed for non-equilibrium organic polymers.
