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From the bottom up--flexible solid state electrochromic devices.

Jacob Jensen1, Frederik C Krebs

  • 1Department of Energy Conversion and Storage, Technical University of Denmark, Frederiksborgvej 399, DK-4000, Roskilde, Denmark.

Advanced Materials (Deerfield Beach, Fla.)
|September 9, 2014
PubMed
Summary
This summary is machine-generated.

Researchers developed a new method for creating flexible polymer-based electrochromic devices using a continuous, one-directional stacking process. This innovative technique avoids lamination and enables fully printed, 2D patterned organic electrochromics.

Keywords:
electrochromic devicesin-situ photo crosslinkingslot-die coatingsolid state electrolyte

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Area of Science:

  • Materials Science
  • Polymer Chemistry
  • Device Engineering

Background:

  • Electrochromic devices (ECDs) offer tunable optical properties but often require complex fabrication.
  • Existing methods for solid-state flexible ECDs can be labor-intensive and limit scalability.
  • The development of continuous, roll-to-roll compatible manufacturing processes is crucial for commercialization.

Purpose of the Study:

  • To develop a novel, continuous fabrication method for solid-state flexible polymer-based electrochromic devices.
  • To eliminate the need for a lamination step in device assembly.
  • To enable the production of fully printed and 2D patterned organic electrochromics.

Main Methods:

  • Fabrication of devices through continuous, one-directional layer stacking.
  • Utilized in situ photo-crosslinking of the polymer electrolyte within a specialized
  • curing-chamber
  • attached to a roll-coater.
  • Controlled reduction of oxygen concentration at the electrolyte surface during photo-crosslinking.

Main Results:

  • Successfully demonstrated a bottom-up fabrication approach for solid-state flexible polymer-based electrochromic devices.
  • Achieved continuous manufacturing without requiring a separate lamination step.
  • Enabled the creation of fully printed and 2D patterned organic electrochromic devices.

Conclusions:

  • The developed in situ photo-crosslinking method is effective for continuous fabrication of flexible polymer ECDs.
  • This approach simplifies the manufacturing process and enhances scalability.
  • The technology paves the way for advanced, printable organic electrochromic applications.