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Fabrication of Periodic Gold Nanocup Arrays Using Colloidal Lithography
Published on: September 2, 2017
Fabrication of periodic silicon nanopillars in a two-dimensional hexagonal array with enhanced control on structural
Jea-Young Choi1, T L Alford1, Christiana B Honsberg1
1†School for Engineering of Matter, Transport and Energy, and ‡School of Electrical, Computer and Energy Engineering, Arizona State University, Tempe, Arizona 85287, United States.
Abstract:
We present a method to fabricate well-controlled periodic silicon nanopillars (Si NPs) in hexagonal arrays using silica nanosphere (SNS) lithography (SNL) combined with metal-assisted chemical etching (MaCE). The period of the Si NPs is easily changed by using our silica nanosphere (SNS) spin-coating process, which provides excellent monolayer uniformity and coverage (>95%) over large surface areas. The size of the deposited SNS is adjusted by reactive ion etching (RIE) to produce a target diameter at a fixed period for control of the surface pattern size after a gold metal mask layer deposition. The Si NPs are etched with the MaCE technique following introduction of a Ni interfacial layer between the Si and Au catalyst layer for adhesion and improved lithographical accuracy. The result is a fast, convenient, and large-area applicable Si surface nanolithography technique for accurate and reproducible Si NP fabrication.

