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Updated: Apr 12, 2026

Ultrafast Time-resolved Near-IR Stimulated Raman Measurements of Functional π-conjugate Systems
Published on: February 10, 2020
Perspective: Stimulated Raman adiabatic passage: The status after 25 years
Klaas Bergmann1, Nikolay V Vitanov2, Bruce W Shore3
1Fachbereich Physik und Forschungszentrum OPTIMAS, Technische Universität Kaiserslautern, Kaiserslautern, Germany.
Stimulated Raman adiabatic passage (STIRAP) offers precise quantum control for molecular dynamics. This technique, developed 25 years ago, has found broad applications in physics and chemistry.
Area of Science:
- Quantum control
- Molecular dynamics
- Spectroscopy
Background:
- The stimulated Raman adiabatic passage (STIRAP) technique was first presented 25 years ago.
- Initially motivated by studying reaction dynamics in vibrationally excited small molecules.
Purpose of the Study:
- To provide a theoretical foundation and experimental validation of STIRAP.
- To review the development and diverse applications of STIRAP.
- To stimulate further research and application of the STIRAP concept.
Main Methods:
- Theoretical framework of STIRAP.
- Experimental demonstration of STIRAP.
- Review of STIRAP applications across various scientific fields.
Main Results:
- STIRAP has achieved significant success and widespread adoption.
- The technique has been successfully applied in diverse areas of physics and chemistry.
- The article discusses the physics behind STIRAP and its evolution.
Conclusions:
- STIRAP is a powerful technique for quantum control with a proven track record.
- Its applications continue to expand, highlighting its versatility.
- Future directions for STIRAP research are promising.
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