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Updated: Apr 12, 2026

Photodeposition of Pd onto Colloidal Au Nanorods by Surface Plasmon Excitation
Published on: August 15, 2019
Effect of trimetallization in thiolate-protected Au(24-n)Cu(n)Pd clusters
Sachil Sharma1, Wataru Kurashige, Katsuyuki Nobusada
1Department of Applied Chemistry, Faculty of Science, Tokyo University of Science, 1-3 Kagurazaka, Shinjuku-ku, Tokyo 162-8601, Japan. negishi@rs.kagu.tus.ac.jp.
Abstract:
We synthesized a mixture of Au24-nCunPd(SC12H25)18 (n = 0-3) and Au25-nCun(SC12H25)18 (n = 0-7) and compared their stability. The results showed that, in a cluster containing one Cu atom, the presence of Pd is effective in improving the cluster stability. Conversely, the presence of Pd has different effects depending on the number of Cu atoms in the cluster: cluster formation was inhibited for clusters containing four or more Cu atoms.

