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A bimetallic iridium(ii) catalyst: [{Ir(IDipp)(H)}2][BF4]2 (IDipp = 1,3-bis(2,6-diisopropylphenylimidazol-2-ylidene))
Laura Rubio-Pérez1, Manuel Iglesias, Julen Munárriz
1Departamento Química Inorgánica - ISQCH, Universidad de Zaragoza - CSIC, 50009 Zaragoza, Spain. miglesia@unizar.es oro@unizar.es.
Chemical Communications (Cambridge, England)
|May 21, 2015
Abstract:
A new Ir(ii) complex [{Ir(μ-κCNHC,η(6)Dipp-IDipp)(H)}2][BF4]2 has been prepared and fully characterised. This complex acts as a catalyst for the hydroalkynylation of imines according to an unprecedented diiridium-mediated mechanism.
