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Updated: Apr 8, 2026

Fabrication and Optimization of Type II Silicon Clathrate Films
Published on: October 14, 2025
Stabilization of Silicon-Carbon Mixed Oxides
Yuzhong Wang1, Mingwei Chen1, Yaoming Xie1
1Department of Chemistry and the Center for Computational Chemistry, The University of Georgia, Athens, Georgia 30602-2556, United States.
Abstract:
The first carbene-stabilized silicon-carbon mixed oxide, (SiO2)2CO2 (4), was synthesized by CO2 oxidation of either carbene-stabilized disilicon, L:Si═Si:L (L: = :C{N(2,6-Pr(i)2C6H3)CH}2) (1), or carbene-stabilized Si2O3 (2) (which can be obtained via N2O oxidation of 1). The structure and bonding of 4 was probed by both experimental and computational methods.
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