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Relationship between Dynamic Planarization Processes and Exciton Delocalization in Cyclic Oligothiophenes.

Pyosang Kim1, Kyu Hyung Park1, Woojae Kim1

  • 1†Spectroscopy Laboratory for Functional π-Electronic Systems and Department of Chemistry, Yonsei University, Seoul 120-749, Korea.

The Journal of Physical Chemistry Letters
|August 12, 2015
PubMed
Summary

Investigating dynamic planarization in cyclic molecules reveals how molecular conformation impacts exciton delocalization. This study clarifies exciton dynamics in π-conjugated systems, offering insights for organic materials design.

Keywords:
bond length alternationconformational heterogeneitiesfluorescence up-conversionlinear and cyclic molecular structuretime-resolved fluorescence spectravibronic band

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