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Updated: Apr 5, 2026
![Cercosporin-Photocatalyzed [4+1]- and [4+2]-Annulations of Azoalkenes Under Mild Conditions](/_next/image?url=https%3A%2F%2Fcloudfront.jove.com%2FCDNSource%2Fteasers%2F60786.jpg&w=3840&q=50)
Cercosporin-Photocatalyzed [4+1]- and [4+2]-Annulations of Azoalkenes Under Mild Conditions
Published on: July 17, 2020
Crystal structure of 2-(4-tert-butyl-phen-yl)-3-hydroxy-4H-chromen-4-one
Fuka Narita1, Akihiro Takura1, Takashi Fujihara2
1Department of Chemistry, Graduate School of Science and Engineering, Saitama University, Shimo-Okubo 255, Sakura-ku, Saitama 338-8570, Japan.
Abstract:
Yellow-green fluorescent crystals of the title compound, C19H18O3, were obtained by the reaction of hy-droxy-aceto-phenone and 4-tert-butyl-benzaldehyde with hydrogen peroxide as oxidant. The plane of the benzene ring is slightly twisted to the mean plane of the 4H-chromene-4-one moiety (r.m.s. deviation = 0.0191 Å) by 10.53 (8)°. In the crystal, mol-ecules are linked by pairs of O-H⋯O hydrogen bonds, forming inversion dimers with an R 2 (2)(10) ring motif. The dimers are linked via C-H⋯π inter-actions, forming sheets parallel to (10-1).
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